Ion Current Rectification, Limiting and Overlimiting Conductances in Nanopores
نویسندگان
چکیده
منابع مشابه
Ion Current Rectification, Limiting and Overlimiting Conductances in Nanopores
Previous reports on Poisson-Nernst-Planck (PNP) simulations of solid-state nanopores have focused on steady state behaviour under simplified boundary conditions. These are Neumann boundary conditions for the voltage at the pore walls, and in some cases also Donnan equilibrium boundary conditions for concentrations and voltages at both entrances of the nanopore. In this paper, we report time-dep...
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Numerical modeling of the coupled ionic and fluidic transport in field-effect gated nanopores reveals highly nonlinear current-voltage characteristics, including cross-over, rectification, and particularly limiting and overlimiting conductance. The limiting and overlimiting characteristics are shown to be greatly enhanced by the inherently coupled fluid flow and correlate with electrokinetic ph...
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proving the validity of the present numerical approach. The results were also compared to the FEM simulations made by White et al. The ion current rectification in the pore of 10 μm length and half-cone angle of 12°, filled with 1 mM KCl solution was simulated. In this case the rectification ratio r(E) 35 is 1.39, while White et al report 1.38. The tiny difference in the obtained result is prob...
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Ionic transport in charged conical nanopores is known to give rise to ion current rectification. The present study shows that the rectification direction can be inverted when using electrolyte solutions at very low ionic strengths. To elucidate these phenomena, electroneutral conical nanopores containing a perm-selective region at the tip have been investigated and shown to behave like classica...
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Herein we report a theoretical study of diode-like behavior of negatively charged (e.g., glass or silica) nanopores at different potential scan rates (1-1000 V·s(-1)). Finite element simulations were used to determine current-voltage characteristics of conical nanopores at various electrolyte concentrations. This study demonstrates that significant changes in rectification behavior can be obser...
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ژورنال
عنوان ژورنال: PLOS ONE
سال: 2015
ISSN: 1932-6203
DOI: 10.1371/journal.pone.0124171